STEEL MANUFACTURE PROCESS
In most of the world, steel is manufactured by integrated steel facilities that produce steel from basic raw materials, i.e., iron ore, coke, and limestone. However, the fastest growing segment of the steel industry is the “minimill” that melts steel scrap as the raw material. Both types of facilities produce a wide variety of steel forms, including sheet, plate, structural, railroad rail, and bar products.
IRONMAKING
When making steel from iron ore, a blast furnace chemically reduces the ore (ironoxide) with carbon in the form of coke. Coke is a spongelike carbon mass that is produced from coal by heating the coal to expel the organic matter and gases. Limestone (calcium carbonate) is added as a flux for easier melting and slag formation.The slag, which floats atop the molten iron, absorbs many of the unwanted impurities. The blast furnace is essentially a tall hollow cylindrical structure with a steel outer shell lined on the inside with special refractory and graphite brick. The crushed or pelletized ore, coke, and limestone are added as layers through an opening at the top of the furnace, and chemical reduction takes place with the aid of a blast of preheated air entering near the bottom of the furnace (an area called the bosh). The air is blown into the furnace through a number of water-cooled copper nozzles called tuyeres. The reduced liquid iron fills the bottom of the furnace and is tapped from the furnace at specified intervals of time. The product of the furnace is called pig iron because in the early days the molten iron was drawn from the furnace and cast directly into branched mold configurations on the cast house floor. The central branch of iron leading from the furnace was called the “sow” and the side branches were called “pigs.” Today the vast majority of pig iron is poured directly from the furnace into a refractory-lined vessel (submarine car) and transported in liquid form to a basic oxygen furnace (BOF) for refinement into steel.
STEELMAKING.
In the BOF, liquid pig iron comprises the main charge. Steel scrap is added to dilute the carbon and other impurities in the pig iron. Oxygen gas is blown into the vessel by means of a top lance submerged below the liquid surface. The oxygen interacts with the molten pig iron to oxidize undesirable elements. These elements include excess carbon (because of the coke used in the blast furnace, pig iron contains over 2% carbon), manganese, and silicon from the ore and limestone and other impurities like sulfur and phosphorus. While in the BOF, the liquid metal is chemically analyzed to determine the level of carbon and impurity removal. When ready, the BOF is tilted and the liquid steel is poured into a refractory-lined ladle.While in the ladle, certain alloying elements can be added to the steel to produce the desired chemical composition. This process takes place in a ladle treatment station or ladle furnace where the steel is maintained at a particular temperature by external heat from electrodes in the lid placed on the ladle. After the desired chemical composition is achieved, the ladle can be placed in a vacuum chamber to remove undesirable gases such as hydrogen and oxygen. This process is called degassing and is used for higher quality steel products such as railroad rail, sheet,plate, bar, and forged products. Stainless steel grades are usually produced in an induction or electric arc furnace, sometimes under vacuum. To refine stainless steel, the argon–oxygen decarburization (AOD) process is used. In the AOD, an argon–oxygen gas mixture is injected through the molten steel to remove carbon without a substantial loss of chromium (the main element in stainless steel).
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